| The electrolytic
deposition of chromium to the surface of other materials,
primarily metals occurs when electrical energy supplied
to electrodes in a solution consisting primary of chromic
acid is converted to chemical energy to produce chromium
metal. Chromium is a desirable metal coating due to its
inherent protective characteristics. A major application
of industrial hard chrome plating is the salvaging of worn or mismachined
parts where chromium is applied to restore the part’s
original dimensions.
ADHESION AND BONDING
Adhesion between a chromium layer and the base metal upon
which it is deposited is achieved by a molecular bond. Bond
strengths in the excess of 35,000 psi are common.
CHROME PLATING IRREGULAR GEOMETRIC SURFACES
During electrodeposition, the current distribution over
different areas of a component greatly varies, depending
upon its geometrical shape. Elevations and peaks, as well
as areas directly facing the anodes, receive a higher current
density than depressions, recesses and areas away from or
not directly facing anodes. The variation in current density
over different areas produces a corresponding variation
in the thickness of the deposited metal.
CHROME THICKNESS
There is no standard thickness for industrial hard chrome plating.
Deposit thickness is generally dictated by economics and
application performance. A thick deposit of chrome is of
value when it provides additional wear surface.
CHROME WEAR RESISTANCE
Wear, defined as deterioration due to use, is affected
by six major factors: impact, abrasion, non-galling friction,
heat, corrosion and vibration. Chrome has three distinct
characteristics that are advantageous in resistant wear:
it is very hard, it is very slippery, and it is resistant
to most industrially corrosive environments.
CORROSION RESISTANCE
Chromium is a hard, brittle, tensile-stressed metal that
is effective in resisting most types of corrosion. As it
builds in thickness, it develops a pattern of tiny cracks
when the stresses become greater than the strength of the
coating. These cracks form an interlacing pattern, which
sometimes extends to the base metal. A corrosive liquid
or gas could penetrate to the base metal. This can be prevented
in three ways: a nickel undercoat can be applied to provide
a corrosion-resisting barrier; the chrome plating can be
applied to maximum thickness; or a thin dense chrome coating
can be substituted.Click Here to view the corrosion resistance chart.
| PROPERTIES
OF INDUSTRIAL HARD CHROME |
| Material |
Chromium plus trace amounts of oxides
and Hydrogen |
| Structure |
Crystalline; fine grained with numerous cracks |
| Internal stress on steel |
200-300 MPa (30-40,000psi) |
| Density |
6.9-7.18 g/cm3 |
| Melting Point |
1610 °C |
| Magnetic Coercity |
Non-magnetic |
| Tensile Strength |
200 MPa (30,000 psi) |
| Ductility |
.1% elongation |
| Modulus of Elasticity |
100-200 GPa (15-30 x 106 psi) |
| Adhesion Strength |
Excellent (35,000 psi) |
| Hardness |
800-1200 VHN100 (68-70 Rc) |
| Coeffiction of Fiction vs. Steel |
.16-.43 lubricated |
| Taber Wear Resistance |
2-3 mg/1000 cycles |
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